They all fire one cylinder about every 720 degrees(+/- for correct timing),same goes for every 4 cylinder and V-8.
with all do respect thats not the way i understand it? because 720 degrees is 12 revolutions of the crankshaft required to fire all six cylinders.
wikapedia link:
http://en.wikipedia.org/wiki/V6_engine
cut and paste from wiki
[edit] Odd and even firing
Many older V6 engines were based on V8 engine designs, in which a pair of cylinders was cut off the front of V8 without altering the V angle or using a more sophisticated crankshaft to even out the firing interval. Most V8 engines share a common crankpin between opposite cylinders in each bank, and a 90° V8 crankshaft has just four pins shared by eight cylinders, with two pistons per crankpin, allowing a cylinder to fire every 90° to achieve smooth operation.
Early 90° V6 engines derived from V8 engines had three shared crankpins arranged at 120° from each other, similar to an inline 3-cylinder. Since the cylinder banks were arranged at 90° to each other, this resulted in a firing pattern with groups of two cylinders separated by 90° of rotation, and groups separated by 150° of rotation, causing a notorious odd-firing behavior, with cylinders firing at alternating 90° and 150° intervals. The uneven firing intervals resulting in rough-running engines with unpleasant harmonic vibrations at certain engine speeds.
An example is the Buick 231 odd-fire, which has a firing order 1-6-5-4-3-2. As the crankshaft is rotated through the 720° required for all cylinders to fire, the following events occur on 30° boundaries:
More modern 90° V6 engines avoid this problem by using split crankpins, with adjacent crankpins offset by 15° in opposite directions to achieve an even 120° ignition pattern. Such a 'split' crankpin is weaker than a straight one, but modern metallurgical techniques can produce a crankshaft that is adequately strong.
In 1977, Buick introduced the new "split-pin crankshaft" in the 231. Using a crankpin that is 'split' and offset by 30° of rotation resulted in smooth, even firing every 120°. However, in 1978 Chevrolet introduced a 90° 200/229 V6, which had a compromise 'semi-even firing' design using a crankpin that was offset by only 18°. This resulted in cylinders firing at 108° and 132°, which had the advantage of reducing vibrations to a more acceptable level and did not require strengthening the crankshaft. In 1985 Chevrolet's 4.3 (later the Vortec 4300) changed it to a true even-firing V6 with a 30° offset, requiring larger crank journals to make them adequately strong.
In 1986 the similarly-designed 90° PRV engine adopted the same 30° crankshaft offset design to even out its firing. In 1998, Mercedes-Benz introduced a V6 engine that not only had split crankpins, but had a counter-rotating balancing shaft between the cylinder banks to eliminate almost all primary and secondary vibrations, resulting in a very smooth-running engine.